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Agrawal, Kirti; Hasan, Syed Mohammad; Blawat, Joanna; Mehta, Nishir; Wang, Yuming; Cueto, Rafael; Siebenbuerger, Miriam; Kizilkaya, Orhan; Prasad, Narasimha S.; Dorman, James; et al (, Chemosensors)Inorganic lead-halide perovskite, cesium lead bromide (CsPbBr3), shows outstanding optoelectronic properties. Both solution- and melt-based methods have been proposed for CsPbBr3 crystal growth. The solution-based growth was done at low-temperature, whereas the melt-based growth was done at high-temperature. However, the comparison of optical, physical, and defect states using these two different growth conditions has been scarcely studied. Here, we have compared the thermal and optical properties of solution-grown and melt-grown single crystals of CsPbBr3. Positron Annihilation Lifetime Spectroscopy (PALS) analysis showed that melt-grown crystal has a relatively smaller number of defects than the chemical synthesis method. In addition, crystals grown using the chemical method showed a higher fluorescence lifetime than melt-grown CsPbBr3.more » « less
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Fameau, Anne-Laure; Ma, Yingzhen; Siebenbuerger, Miriam; Bharti, Bhuvnesh (, Journal of Colloid and Interface Science)
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